Gold-catalysed glycosylation reaction using an easily accessible leaving group.
نویسندگان
چکیده
Gold(III)-catalysed glycosylation reaction has been developed by employing a new and easily accessible leaving group synthesized from ethyl cyanoacetate. Several nucleophiles like alcohols, thiols, allyltrimethylsilane, trimethylsilyl azide and triethylsilane have been reacted to make the corresponding glycosides in good yields and with marginal to excellent α-selectivity.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 13 18 شماره
صفحات -
تاریخ انتشار 2015